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Diiodomethane : MI : Methylene Iodide - Simmons Smith Reaction [ CAS: 75-11-6 ] - 50g

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Description

Diiodomethane
Other Names: Methylene iodide, Diiodomethylene

CAS Number: 75-11-6
Sum Formula: CH₂I₂
Molar Mass: 267.84 g/mol
Appearance: Colorless to pale yellow liquid (darkens upon exposure to light)

Diiodomethane is a dense, halogenated organic compound composed of one carbon atom bonded to two iodine atoms and two hydrogen atoms. It is used in a range of chemical and industrial applications, particularly as a solvent and a reagent in synthesis and density-based separation techniques.


Chemical and Physical Properties

Density: 3.32 g/cm³ at 20°C
Melting Point: 6.2°C
Boiling Point: 181–182°C
Solubility in Water: Slightly soluble
Solubility in Other Solvents: Soluble in ethanol, ether, and chloroform
Odor: Sweet, penetrating odor
Light Sensitivity: Darkens on exposure to light


Applications

Organic Synthesis: Used as a reagent in the cyclopropanation of alkenes and in other halogenation reactions.

Density Separation: Applied in mineralogy and material science to separate mixtures based on density due to its high specific gravity.

Spectroscopy and Optical Research: Occasionally used in refractive index studies and as a reference liquid.

Chemical Research: Employed in specialized laboratory reactions requiring highly halogenated solvents.


Safety

Signal Word: Danger

 

GHS Hazard Statements

H302 (93.2%): Harmful if swallowed [Warning Acute toxicity, oral]

H315 (36.9%): Causes skin irritation [Warning Skin corrosion/irritation]

H318 (29%): Causes serious eye damage [Danger Serious eye damage/eye irritation]

H335 (36.9%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

H412 (59.7%): Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]

Precautionary Statement Codes

P261, P264, P264+P265, P270, P271, P273, P280, P301+P317, P302+P352, P304+P340, P305+P354+P338, P317, P319, P321, P330, P332+P317, P362+P364, P403+P233, P405, and P501


First Aid Measures

Eye Contact: Rinse thoroughly with water for several minutes. Seek immediate medical attention.
Skin Contact: Wash with soap and water. Remove contaminated clothing. Seek medical help if irritation occurs.
Inhalation: Move to fresh air. Seek medical attention if breathing becomes difficult.
Ingestion: Rinse mouth. Do not induce vomiting. Seek immediate medical attention.


Handling and Storage

Storage Conditions: Store in a tightly closed amber glass container in a cool, dry, and well-ventilated place. Protect from light and moisture.
Handling Precautions: Avoid inhalation and contact with skin or eyes. Use proper ventilation and protective equipment when handling.

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