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Bismuth (III) Chloride

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Description

Bismuth(III) Chloride
Other Names: Bismuth trichloride, Trichlorobismuthane

CAS Number: 7787-60-2
Sum Formula: BiCl₃
Molar Mass: 315.34 g/mol
Appearance: White to yellowish crystalline solid, may appear slightly hygroscopic

Bismuth(III) chloride is an inorganic halide of bismuth in its +3 oxidation state. It hydrolyzes in moist air and water to form oxychlorides and is primarily used in synthesis, analytical chemistry, and materials science.

Chemical and Physical Properties
Density: 4.75 g/cm³
Melting Point: 227°C
Boiling Point: 447°C (decomposes)
Solubility in Water: Reacts with water, forming insoluble oxychloride
Solubility in Other Solvents: Soluble in hydrochloric acid and alcohol; decomposes in moist air
Odor: Odorless

Applications
Inorganic Synthesis: Used as a precursor to bismuth-based compounds.
Catalysis: Employed in organic transformations and chlorination reactions.
Analytical Chemistry: Acts as a reagent for detecting specific ions or functional groups.
Material Science: Utilized in research and fabrication of electronic and optical materials.

Safety

Signal Word: Warning

GHS Hazard Statements

H315 (96.2%): Causes skin irritation [Warning Skin corrosion/irritation]

H319 (96.2%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]

Precautionary Statement Codes

P264, P264+P265, P280, P302+P352, P305+P351+P338, P321, P332+P317, P337+P317, and P362+P364

Handling and Storage
Storage Conditions: Store in a tightly closed container in a dry, cool, and well-ventilated area. Protect from moisture, as it hydrolyzes in humid air.
Handling Precautions: Avoid dust formation and contact with water. Handle under dry conditions with appropriate protective equipment and ventilation.

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