Dichromian amonu

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Opis

Ammonium Dichromate
Other Names: Dichromic acid, ammonium salt; (NH₄)₂Cr₂O₇
CAS Number: 7789-09-5
Chemical Formula: (NH₄)₂Cr₂O₇
Molar Mass: 252.06 g/mol
Appearance: Bright orange to red-orange crystalline solid

Description:
Ammonium dichromate is a crystalline, highly oxidizing inorganic compound composed of ammonium and dichromate ions. It is well known for its vigorous thermal decomposition, producing sparks and a dark green residue of chromium(III) oxide. It is primarily used in pyrotechnics, photography, lithography, and as a laboratory reagent.

Chemical and Physical Properties

  • Density: 2.15 g/cm³

  • Melting Point: 170°C (decomposes)

  • Boiling Point: Not applicable (decomposes before boiling)

  • Solubility in Water: 285 g/L at 20°C (very soluble)

  • Solubility in Other Solvents: Slightly soluble in alcohol

  • Odor: Odorless or slight ammonia smell

Applications

  • Pyrotechnics: Produces heat, sparks, and colored flames in fireworks and chemical demonstrations.

  • Analytical Chemistry: Used in volumetric analysis and as an oxidizing agent.

  • Photography and Lithography: Historically used in sensitizing processes.

  • Demonstrations: Famous for the "volcano" decomposition experiment in teaching.

Safety


Signal Word: Danger

GHS Hazard Statements

H272 (99.5%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]

H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]

H312 (100%): Harmful in contact with skin [Warning Acute toxicity, dermal]

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

H317 (100%): May cause an allergic skin reaction [Warning Sensitization, Skin]

H318 (54.1%): Causes serious eye damage [Danger Serious eye damage/eye irritation]

H330 (100%): Fatal if inhaled [Danger Acute toxicity, inhalation]

H334 (100%): May cause allergy or asthma symptoms or breathing difficulties if inhaled [Danger Sensitization, respiratory]

H340 (100%): May cause genetic defects [Danger Germ cell mutagenicity]

H350 (100%): May cause cancer [Danger Carcinogenicity]

H360 (45.9%): May damage fertility or the unborn child [Danger Reproductive toxicity]

H360FD (53.6%): May damage fertility; May damage the unborn child [Danger Reproductive toxicity]

H372 (100%): Causes damage to organs through prolonged or repeated exposure [Danger Specific target organ toxicity, repeated exposure]

H400 (99.5%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]

H410 (100%): Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]

Precautionary Statement Codes

P203, P210, P220, P233, P260, P261, P264, P264+P265, P270, P271, P272, P273, P280, P284, P301+P316, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P318, P319, P320, P321, P330, P333+P317, P342+P316, P362+P364, P363, P370+P378, P391, P403, P403+P233, P405, and P501

Handling and Storage

  • Handling Precautions: Handle with extreme care in a well-ventilated area. Avoid inhalation and contact with skin or eyes. Do not mix with combustible materials.

  • Storage Conditions: Store in a tightly closed container in a cool, dry, well-ventilated area away from incompatible substances such as reducing agents, organic materials, and strong acids.

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